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・ Phosphorus selenide
・ Phosphorus sesquisulfide
・ Phosphorus sulfide
・ Phosphorus tribromide
・ Phosphorus tribromide (data page)
・ Phosphorus trichloride
・ Phosphorus trichloride (data page)
・ Phosphorus trifluoride
・ Phosphorus trifluoride (data page)
・ Phosphorus triiodide
・ Phosphorus triiodide (data page)
・ Phosphorus trioxide
・ Phosphorus trisulfide
・ Phosphorus-31 nuclear magnetic resonance
・ Phosphorus-32
Phosphoryl bromide
・ Phosphoryl chloride
・ Phosphoryl chloride (data page)
・ Phosphoryl fluoride
・ Phosphoryl group
・ Phosphoryl nitride
・ Phosphorylase
・ Phosphorylase kinase
・ Phosphorylase kinase, alpha 1
・ Phosphorylation
・ Phosphorylation cascade
・ Phosphorylcholine
・ Phosphorylethanolamine
・ Phosphoserine
・ Phosphoserine phosphatase


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Phosphoryl bromide : ウィキペディア英語版
Phosphoryl bromide

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Phosphoryl bromide, also known as phosphorus oxybromide, is an inorganic compound with the formula POBr3. It can be prepared via the slow addition of liquid bromine to phosphorus tribromide at 0 °C, followed by the slow addition of water and vacuum distillation of the resulting slurry.
It is prepared according to the equation: 3 PBr5 + P2O5 → 5 POBr3〔Hönigschmid, Hirschbold-Wittner, Z. Anorg. Allg. Chem. 243, 355 (1940)〕〔Johnson, Nunn, J. Am. Chem. Soc. 63, 141 (1941); Booth, Seegmiller, Inorg. Synth. 2, 151 (1946)〕
==Properties==
Thin plates, faint orange tint, d 2.822. mp 56° (in hot water). bp758 193° (decomposes). Slowly hydrolyzes in water forming H3PO4 and HBr. Soluble in ether, benzene, chloroform, carbon disulfide, concentrated H2SO4. Store in sealed glass ampoules.

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